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Ethyl Formate

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    Specialty Chemicals

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Product Profile

Ethyl Formate (Ethyl Methanoate)

   CAS No.: 109-94-4
   Synonyms / IUPAC Name: Ethyl Formate, Ethyl Methanoate
   Molecular Formula: C₃H₆O₂
   Molecular Weight: 74.08 g/mol


Physicochemical Properties (Typical)

  • Appearance: Colorless, clear liquid
  • Odor: Pleasant, fruity or rum-like odor
  • Melting Point: –80 °C
  • Boiling Point: 54 °C
  • Density (20 °C): 0.92 g/cm³
  • Vapor Pressure (20 °C): 200 mmHg
  • Solubility in Water (20 °C): Moderate (~10%)
  • Solubility in Organic Solvents: Miscible with alcohols, ethers, acetone, and benzene
  • Flash Point: –20 °C (closed cup)
  • Autoignition Temperature: 440 °C
  • Explosive Limits (v/v in air): 2.8% – 16%
  • Refractive Index (n²⁰ᴰ): 1.361
  • Stability: Stable under normal storage; slowly hydrolyzes in water to form formic acid and ethanol

Purity & Quality Standards

  • Purity (by GC): ≥98.0%
  • Water / Moisture Content: ≤0.5%
  • Acid Value (as Formic Acid): ≤0.01%
  • Non-volatile Residue: ≤0.01%
  • Heavy Metals: ≤0.001%
  • Analytical Methods: Gas chromatography, spectroscopy, titration
  • Documentation: Certificate of Analysis (COA) and Safety Data Sheet (SDS) provided

Applications / Uses

  • Solvent for nitrocellulose, resins, oils, and waxes
  • Intermediate in organic synthesis and esterification processes
  • Used as fumigant or insecticidal agent in grain and commodity storage
  • Flavor and fragrance applications under controlled regulatory limits

Safety & Handling

  • Hazard Classification: Flammable liquid, Class 3
  • Health Hazards: Causes eye and skin irritation; inhalation may cause dizziness and respiratory irritation
  • Exposure Limits: TWA 100 ppm; STEL 150 ppm; IDLH 1500 ppm
  • Precautions: Use in well-ventilated areas; avoid sources of ignition; wear gloves, goggles, and protective clothing
  • Fire & Explosion: Vapors may form explosive mixtures with air; use non-sparking tools and explosion-proof equipment
  • Reactivity: Incompatible with strong oxidizers, acids, and bases
  • First Aid Measures:
    • Inhalation – Move to fresh air
    • Skin – Wash with water and soap
    • Eyes – Flush with water for at least 15 minutes
    • Ingestion – Seek immediate medical attention

Packaging & Storage

  • Packaging: Sealed metal drums or approved solvent containers
  • Storage Conditions: Cool, dry, and well-ventilated area; away from heat, sparks, or open flames
  • Container Closure: Keep tightly sealed to prevent vapor loss
  • Storage Temperature: Ideally below 30 °C
  • Shelf Life: 12–24 months under proper storage