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Diethanolamine

  • Category:
    Aliphatic Amines

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Product Profile

1. Chemical Structure and Properties

Molecular Formula: C₄H₁₁NO₂
Structural Formula: HN(CH₂CH₂OH)₂ — A secondary aliphatic amine with two hydroxyethyl groups attached to the nitrogen atom.

Physical Properties:

  • Appearance: Colorless to pale yellow viscous liquid

  • Boiling Point: ~269°C

  • Density: 1.09 g/cm³ at 20°C

  • Solubility: Miscible with water, alcohols, and many polar organic solvents

Chemical Properties:

  • Acts as a weakly basic secondary amine with two hydroxyl groups

  • Exhibits both nucleophilic and amphiphilic behavior

  • Stable under normal conditions, reactive with strong oxidizers

  • Flash point: ~104°C (closed cup) — combustible but less volatile than low molecular weight amines


2. Industrial Applications

Gas Treatment:

  • Widely used in natural gas and refinery industries for CO₂ and H₂S absorption

Corrosion Inhibition:

  • Added to boiler water, cooling systems, and metalworking fluids to neutralize acidic impurities

Chemical Intermediate:

  • Key raw material in producing surfactants, emulsifiers, and other specialty chemicals

Personal Care & Pharmaceuticals:

  • Used as a pH regulator and intermediate in cosmetics, shampoos, and pharmaceutical formulations

Textile and Leather Processing:

  • Acts as a buffering agent and pH adjuster in dyeing, finishing, and leather treatment


3. Safety and Toxicology

Health Hazards:

  • Skin/Eye Contact: May cause irritation; prolonged exposure can lead to dermatitis

  • Inhalation: Vapors may irritate respiratory tract

  • Ingestion: Harmful if swallowed

Fire & Explosion Risk:

  • Combustible liquid; avoid open flames and ignition sources

Protective Measures:

  • Wear nitrile gloves, chemical-resistant goggles, and proper respiratory protection

  • In case of contact, rinse thoroughly with water and seek medical advice if irritation persists


4. Environmental and Regulatory Considerations

Environmental Impact:

  • Biodegradable under aerobic conditions

  • Moderate aquatic toxicity; avoid release into waterways

Regulatory Compliance:

  • Registered under EU REACH and listed on US TSCA

  • Transport classification: UN 2923, Class 8 (corrosive), Packing Group III


5. Case Studies and Application Insights

Gas Sweetening:

  • Employed in acid gas removal units to capture CO₂ and H₂S, improving fuel quality and reducing emissions

Corrosion Control:

  • Incorporated in cooling towers and boiler water treatment, prolonging equipment life and lowering maintenance costs

Comparison with Alternatives:

  • Compared to monoethanolamine (MEA), DEA offers lower volatility and better thermal stability, making it suitable for harsher industrial conditions