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Azobisisobutyronitrile

  • Category:
    Specialty Chemicals

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Product Profile

  1. Chemical Structure and Properties

  • Molecular Formula: C₈H₁₂N₄

  • Structural Formula: (CH₃)₂C(CN)–N=N–C(CN)(CH₃)₂

  • Appearance: White to pale yellow crystalline powder

  • Melting Point: 105–110°C

  • Density: 1.0 g/cm³

  • Solubility: Slightly soluble in water; soluble in organic solvents such as ethanol, acetone, and ether

  • Chemical Properties:

    • Organic azo compound with a –N=N– functional group

    • Decomposes thermally to release nitrogen gas, generating free radicals

    • Stable under standard conditions but sensitive to heat, friction, and shock

  1. Industrial Applications

  • Polymerization Initiator: Widely used as a radical initiator in polymerization of acrylics, styrenics, and vinyl monomers

  • Plastic and Rubber Manufacturing: Initiates crosslinking reactions in plastics and synthetic rubber

  • Specialty Chemical Synthesis: Used as a reagent in organic synthesis for free radical reactions

  • Laboratory Use: Commonly employed in research for radical polymerizations and as a source of radicals

  1. Safety and Toxicology

  • Health Hazards: May cause skin and eye irritation; inhalation of dust can irritate respiratory tract

  • Fire & Explosion Risk: Explosive under heat or friction; emits toxic fumes upon decomposition

  • Protective Measures: Handle in well-ventilated areas; use gloves, safety goggles, and avoid heat sources

  1. Environmental and Regulatory Considerations

  • Environmental Impact: Avoid release into waterways; biodegradable under aerobic conditions is limited

  • Regulatory Compliance: Classified as hazardous under GHS; transport as Class 4.1 (flammable solid)

  1. Case Studies / Application Insights

  • Polymer Industry: Efficiently initiates radical polymerizations, improving molecular weight control and polymer uniformity

  • Alternative Comparison: Compared to benzoyl peroxide, AIBN provides a cleaner radical source with fewer by-products in specific polymerizations


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