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  • DLA
  • DLA

Dimethyl lauryl amine (DLA)

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    Amine Derivatives

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Product Profile

1. Chemical Structure and Properties

Molecular Formula: C₁₄H₃₁N

Structural Formula: CH₃(CH₂)₁₁N(CH₃)₂ — a tertiary amine with a C12 (lauryl) alkyl chain and two methyl groups

Physical Properties:
 Appearance: Colorless to pale yellow liquid with a faint amine odor
 Boiling Point: ~250–270°C; Density: ~0.80–0.82 g/cm³
 Solubility: Insoluble in water; soluble in ethanol, acetone, and hydrocarbons

Chemical Properties:
 - Weak base (pKa ~10.0); reacts with acids to form quaternary ammonium salts
 - Hydrophobic: Long alkyl chain enables surfactant behavior and micelle formation

2. Industrial Applications

Surfactant Production:
 - Key intermediate in cationic surfactants such as lauryl dimethyl benzyl ammonium chloride
 - Common in fabric softeners, disinfectants, and antistatic formulations

Personal Care Products:
 - Used as emulsifier and conditioning agent in hair conditioners and creams
 - Forms a cationic layer on hair to reduce frizz and enhance softness

Oilfield Chemicals:
 - Acts as a corrosion inhibitor and demulsifier in crude oil separation

Agricultural Chemicals:
 - Serves as a precursor in herbicide emulsifiers and pesticide adjuvants

3. Safety and Toxicology

Health Hazards:
 - Skin/Eye: Causes irritation; prolonged exposure may lead to dermatitis
 - Inhalation: May irritate respiratory tract; avoid confined spaces
 - Ingestion: Low acute toxicity (LD50 oral, rat ~2,000 mg/kg); may cause nausea

Environmental Impact:
 - Toxic to aquatic organisms (EC50 algae: ~5–10 mg/L)
 - Biodegradability: >60% in 28 days (OECD 301D)

Protective Measures:
 - PPE: Use nitrile gloves, goggles, and operate under proper ventilation
 - Spill Response: Absorb with inert material; dispose of as hazardous waste

4. Environmental and Regulatory Considerations

EU: REACH-registered; restricted for use in persistent surfactant systems

USA: TSCA-listed; EPA mandates aquatic hazard labeling

China: Listed under IECSC chemical inventory

Transportation: UN 3082 — Environmentally Hazardous Substance, Liquid (marine pollutant)

5. Case Studies: Application Insights

Fabric Softeners:
 - Procter & Gamble’s Downy® uses DLA-derived cationic surfactants to reduce static by 70% at 8% formulation level

Oilfield Demulsifiers:
 - Shell applies DLA-based demulsifiers to separate 95% water from crude oil at 100 ppm dosage

Comparative Analysis:
 - DLA offers strong hydrophobicity for industrial-grade surfactants
 - Cocamidopropyl-based analogs are milder but less resistant to acid and heat